Here are a couple of interesting results from spectral graph theory. Let G be a connected graph and A be its adjacency matrix.
1. G is bipartite if and only if the eigenvalues of A are symmetric about 0.
2. Let D be the maximum degree of a vertex of G. Then G is regular if and only if D is an eigenvalue of A.
3. If A has N distinct eigenvalues, then the diameter of G is strictly less than N.